2,4,6-Trinitrophenyl benzoate
نویسندگان
چکیده
In the title mol-ecule, C13H7N3O8, the phenyl and benzene rings are rotated from the mean plane of the central ester group by 18.41 (9) and 81.80 (5)°, respectively. The dihedral angle between the rings is 80.12 (14)°. In the crystal, mol-ecules are linked by weak C-H⋯O inter-actions, forming helical chains along [010].
منابع مشابه
2,4,6-Trinitrophenyl 3-methylbenzoate
In the title benzoate derivative, C(14)H(9)N(3)O(8), the benzene rings form a dihedral angle of 87.48 (5)°. The central ester unit forms an angle of 19.42 (7)° with the methyl-benzene ring, indicating a significant twist. In the crystal, the mol-ecules are linked by weak C-H⋯O inter-actions forming a helical chain along [010].
متن کامل2,4,6-Trinitrophenyl 4-chlorobenzoate
In the title benzoate derivative, C13H6ClN3O8, the planes of the benzene rings form a dihedral angle of 63.46 (5)°. The dihedral angles between the benzene ring and its nitro groups are 12.78 (16)° for the first ortho, 28.4 (4) and 17.4 (4)° for the second (disordered) ortho and 3.58 (16)° for the para nitro group. The central ester moiety, -C-(C=O)-O-, is essentially planar (r.m.s. deviation f...
متن کامل2,4,6-Trinitrophenyl 4-methylbenzoate
In the title compound, C(14)H(9)N(3)O(8), the benzene rings form a dihedral angle of 69.02 (5)°. The central ester group is rotated by 25.86 (9)° relative to the p-tolyl group. In the crystal, the mol-ecules are linked by C-H⋯O inter-actions into helical chains along [010].
متن کامل4-[(E)-2-(2,4,6-Trinitrophenyl)ethylidene]benzonitrile
In the crystal of the title compound, C(15)H(8)N(4)O(6), the mol-ecules are organized in layers due to their linkage by weak C-H⋯N hydrogen bonds. The layers are themselves inter-connected by weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.8690 (15) and 3.9017 (16) Å]. The dihedral angle between the rings is 31.9 (1)°.
متن کاملTriethylammonium 1,3-dimethyl-5-(2,4,6-trinitrophenyl)barbiturate
In the title mol-ecular salt [systematic name: triethyl-ammonium 1,3-dimethyl-2,6-dioxo-5-(2,4,6-trinitro-phen-yl)-1,2,3,6-tetra-hydro-pyrimidin-4-olate], C(6)H(16)N(+)·C(12)H(8)N(5)O(9) (-), the dihedral angle between the aromatic rings in the anion is 46.88 (8)°. The nitro group para to the ring junction is almost coplanar with its attached ring [dihedral angle = 0.76 (3)°], but the two ortho...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012